| CAS No.: | 72162-23-3 |
|---|---|
| Formula: | C33h60o12 |
| EINECS: | 276-431-5 |
| Appearance: | Powder |
| Usage: | Oil Drilling Auxiliary Agent, Water Treatment Chemicals, Rubber Auxiliary Agents, Plastic Auxiliary Agents, Coating Auxiliary Agents, Textile Auxiliary Agents, Paper Chemicals, Surfactants, Leather Auxiliary Agents, Electronics Chemicals |
| Color: | White |
| Samples: |
|---|
| Customization: |
|---|
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Audited Supplier Technical Data Sheet
| Blend of C10 through C12 dibasic acids.( Corrosion Inhibitor) | |||||
| Application | |||||
| • Metal cutting fluids | • Cooling fluids | • Lubricants | |||
| General Information | |||||
| Formula | Sebacic Acid | Undecanedioic Acid | Dodecanedioic Acid | ||
| CAS Number | 111-20-6 | 1852-04-6 | 693-23-2 | ||
| EINECS Number | 203-845-5 | 211-440-6 | 211-746-3 | ||
| Harmonized Number | 2917-13-0030 | 2917-1900 | 2917-19-7050 | ||
| Specification | |||||
| Appearance |
White/Off white flake |
||||
| Total dibasic acids (wt %) |
≥98.0 |
||||
| C10 through C12 dibasic acid (wt %) |
≥95.0 |
||||
| Water (wt %) |
<0.5 |
||||
| Water Solubility (25ºC) (wt %) |
|
||||
| as dibasic acid |
<0.05 |
||||
| as TEA amine salt |
>10 |
||||
| Typical Analysis | |||||
| Sebacic Acid (wt %) |
8-11 |
||||
| Undecanedioic Acid (wt %) |
47-52 |
||||
| Dodecanedioic Acid (wt %) |
39-42 |
||||
| >C12 Diacids (wt %) |
<2 |
||||
| Monobasic Acid (wt %) |
<0.3 |
||||
| Nitrites |
Non-detectable |
||||
| Acid Value mg KOH/g |
500-510 |
||||
| Melting Point (ºC) |
95-120 |
||||
| Specific Gravity (g/cm3) |
1.02 |
||||
| Shipping Information | |||||
| DOT Shipping Name |
Dodecanedioic Acid blend |
||||
| DOT Hazard Classification |
Not regulated |
||||
| Freight Classification |
Dodecanedioic Acid blend |
||||
Safety Data Sheet
According to Regulation (EC) No 1907/2006
C10-12 Alkanedioic acid
Version 6.0
Issue date: 22/02/2016
Revision date: 22/02/2016
Section 1 Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier:
Identification on the label/Trade name: Pure Mix II
Additional identification: Mixture of long-chain dibasic acids
Identification of the product: See section 3
Index Number: See section 3
REACH registration No.: See section 3
1.2 Relevant identified uses of the substance and uses advised against:
1.2.1 Identified uses:
PROC 1: Use in closed process, no likelihood of exposure.
PROC 2: Use in closed, continuous process with occasional controlled exposure.
PROC 3: Use in closed batch process (synthesis or formulation).
PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises.
PROC 7: Spraying in industrial settings and applications
PROC 8a: Transfer of substance or preparation (charging/discharging) from/to.
PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities.
PROC 14: Production of preparations or articles by tabletting, compression, extrusion, pelletisation.
PROC 15:Use as laboratory reagent
PROC 23:Open processing and transfer operations with minerals/metals at elevated temperature
1.2.2 Uses advised against:
Not available
Section 2 Hazards Identification
2.1 Classification of the substance/mixture:
2.1.1 Classification:
The mixture is classified as following according to REGULATION (EC) No 1272/2008:
| REGULATION (EC) No 1272/2008 | |
| Hazard classes/Hazard categories | Hazard codes |
| Eye Irrit.2 | H319 |
For full text of H- phrases: see section 2.2.
2.2 label elements:
Hazard Pictograms:
Signal Word(S): Warning
Hazard Statement: H319: Causes serious eye irritation
Precautionary statement: P264: Wash hands thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313: If eye irritation persists: Get medical advice/attention.
2.3 Other hazards:
Not available.
Section 3 Composition/information on ingredients
Substance/Mixture: Mixture
Ingredient(s):
| Chemical Name | REACH Registration /pre-registration No. | CAS No. | EC No. | Concentration | classifications |
| SEBACIC ACID | 17-2119938919-17-0000 | 111-20-6 | 203-845-5 | 8 -12% | Not Classified |
| UNDECANEDIOIC ACID | 01-2119983505-29-0000 | 1852-04-6 | 217-440-6 | 47 - 52% | H319 |
| DODECANEDIOIC ACID | 01-2119543732-40-0004 | 693-23-2 | 211-746-3 | 38 - 42% | H319 |
Section 4 First aid measures
4.1 Description of first aid measures:
In all cases of doubt, or when symptoms persist, seek medical attention.
4.1.1 In case of inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
4.1.2 In case of skin contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
4.1.3 In case of eyes contact:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
aid immediately.
Product name: Pure Mix II SDS EU
Version #: 6.0 Issue date: 22-02-2016. Revision date: 22-02-2016. 3 / 7
4.1.4 In case of ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
4.2 Most important symptoms and effects, both acute and delayed:
Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed:
If skin irritation or rash occurs, get medical advice/attention.
Section 5 Fire-Fighting measures
5.1 Extinguishing media:
Suitable extinguishing media: Use water spray, dry chemical foam, or chemical foam.
Unsuitable extinguishing media: Not available.
5.2 Special hazards arising from the
substance or mixture
In case of fire, the following can be released: Carbon monoxide and carbon dioxide.
5.3 Advice for firefighters: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6 Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
6.1.1 For non-emergency personnel: Remove ignition sources. Provide adequate ventilation. Avoid inhalation of vapour
or dust. Avoid skin and eye contact. Wear protective gloves/protective clothing/eye
protection/face protection.
6.1.2 For emergency responders: Wear an appropriate NIOSH/MSHA approved respirator if dust is generated.
6.2 Environmental Precautions: Avoid disposing into drainage/sewer system or directly into the aquatic
environment. Keeping away from drains, surface-and ground-water and soil.
6.3 Methods for Containment and Cleaning
up:
Remove source of heat, sparks, flame, impact, friction or electricity. Avoid raising
dust. Dike spill.
Recover undamaged and minimally contaminated material for reuse and
reclamation. Shovel or sweep up. Place in suitable containers for disposal or
reclamation.
6.4 Reference to other sections: See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
Section 7 Handling and storage
7.1 Precautions for safe handling:
7.1.1 Protective measures: Work clothes, helmet and protective gloves have to be used. Furthermore protective
goggles should always to be worn because of the irritating properties of the product
to eyes.
If dust formation is possible during filling/transfer/charging or discharging operations
LEV (effectiveness 90%) or half mask respirators with dust filters (effectiveness
90%) is required.
7.1.2 Advice on general occupational
hygiene:
Do not eat, drink and smoke in work areas. Wash hands after use. Remove
contaminated clothing and protective equipment before entering eating areas.
7.2 Conditions for safe storage, including
any incompatibilities:
Do not mix with strong oxidants. Store in a cool and well ventilated place. Keep
container tightly closed.
7.3 Specific end use(s): Not applicable.
Section 8 Exposure Controls/Personal Protection
8.1 Control parameters:
8.1.1 Occupational exposure limits: SEBACIC ACID(CAS#1852-04-6): Long-term exposure limit (TWA): 4mg/m3
8.1.2 Additional exposure limits under the
conditions of use:
Not available.
8.1.3 DNEL/DMEL and PNEC-Values: Not available.
8.2 Exposure controls:
8.2.1Appropriate engineering controls: Provide sufficient ventilation to keep employee exposure below recommended
limits.
8.2.2 Individual protection measures, such as personal protective equipment:
Eye/face protection: Wear chemical safety goggles to prevent eye exposure.
Hand protection: Wear appropriate protective gloves to prevent skin exposure.
Body protection: Wear appropriate protective clothing to prevent skin exposure.
Respiratory protection: Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU). Where risk assessment
shows air-purifying respirators are appropriate use a dust mask type N95 (US) or
type P1 (EN 143) respirator.
Thermal hazards: Wear suitable protective clothing to prevent heat.
8.2.3 Environmental exposure controls: Avoid discharge into the environment.
According to local regulations, Federal and official regulations.
Section 9 Physical and chemical properties
9.1 Information on basic physical and chemical properties:
Appearance: Solid flakes
Colour: Off-white / cream
Odour: Odorless
Odour threshold: Not available
pH: Not available
Melting point/range (°C): 90-134°C
Boiling point/range (°C): Not available
Flash point (°C): Not available
Evaporation rate: Not available
Flammability limit - lower (%): Not available
Flammability (solid, gas): Not available
Ignition temperature (°C): Not available
Upper/lower flammability/explosive limits: Not available
Vapour pressure (20°C): 0.0000044 hPa
Vapour density: Not available
Bulk density (kg/m3): 0.5g/cm3
Water solubility (g/l): Not available
n-Octanol/Water (log Po/w): log Pow=2.8 (25 °C) (CAS#1852-04-6)
Auto-ignition temperature: Not available
Decomposition temperature: 259.2°C (CAS#1852-04-6)
Viscosity, dynamic (mPa.s): Not available
Explosive properties: Not available
Oxidising properties: Not available
Molecular Formula: Not available
Molecular Weight: Not available
9.2. Other information:
Fat solubility(solvent- oil to be specified)
etc:
Not available
Surface tension: Not available
Dissociation constant in water( pKa): pKa1: 4.45 - 4.58; pKa2: 5.05 - 5.18 (CAS#693-23-2)
Oxidation-reduction Potential: Not available
Specific gravity: Not available
Section 10 Stability and reactivity
10.1 Reactivity: The substance is stable under normal storage and handling conditions.
10.2 Chemical stability: Stable at room temperature in closed containers under normal storage and handling
conditions.
10.3 Possibility of hazardous reactions: No dangerous reactions known.
10.4 Conditions to avoid: Incompatible materials.
10.5 Incompatible materials: Strong oxidizing agents, reducing agents.
10.6 Hazardous decomposition products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Section 11 Toxicological information
11.1 Information on toxicological effects:
Acute toxicity:
UNDECANEDIOIC ACID (CAS#1852-04-6)
LD50(Oral, Rat): > 5 000 mg/kg bw
LD50(Dermal, Rabbit): > 6 000 mg/kg bw (Male)
LC50(Inhalation, Rat): Not available
SEBACIC ACID (CAS#111-20-6)
LD50(Oral, Rat): > 5 000 mg/kg bw
LD50(Dermal, Rat): > 2 000 mg/kg bw
LC50(Inhalation, Rat): Not available
DODECANEDIOIC ACID (CAS#693-23-2)
LD50(Oral, Rat): > 3 000 mg/kg bw
LD50(Dermal, Rabbit): > 6 000 mg/kg bw (Male)
LC50(Inhalation, Rat): Not available
Skin corrosion/Irritation: Not classified
Serious eye damage/irritation: Causes serious eye irritation.
Respiratory or skin sensitization: Not classified
Germ cell mutagenicity: Not classified
Carcinogenicity: Not classified
Reproductive toxicity: Not classified
STOT- single exposure: Not classified
STOT-repeated exposure: Not classified
Aspiration hazard: Not classified
Section 12 Ecological information
12.1 Toxicity:
UNDECANEDIOIC ACID (CAS#1852-04-6)
| Acute toxicity | Time | Species | Method | Evaluation | Remarks | |
|
LC50 |
>100 mg/L |
96h |
Fish |
OECD 203 |
N/A |
N/A |
|
EC50 |
>100 mg/L |
48h |
Daphnia |
OECD 202 |
N/A |
N/A |
|
EC50 |
N/A |
72h |
Algae |
OECD 201 |
N/A |
N/A |
SEBACIC ACID (CAS#111-20-6)
| Acute toxicity | Time | Species | Method | Evaluation | Remarks | |
|
LC50 |
>100 mg/L |
96h |
Fish |
OECD 203 |
N/A |
N/A |
|
EC50 |
>100 mg/L |
48h |
Daphnia |
OECD 202 |
N/A |
N/A |
|
EC50 |
N/A |
72h |
Algae |
OECD 201 |
N/A |
N/A |
DODECANEDIOIC ACID (CAS#693-23-2)
| Acute toxicity | Time | Species | Method | Evaluation | Remarks | |
|
LC50 |
>840mg/l |
48h |
Fish |
OECD 203 |
N/A |
N/A |
|
EC50 |
>27.6mg/l |
24h |
Daphnia |
OECD 202 |
N/A |
N/A |
|
EC50 |
38.6 mg/l |
72h |
Algae |
OECD 201 |
N/A |
N/A |
12.2 Persistence and degradability: Readily biodegradable.
12.3 Bioaccumulative potential: Not available.
12.4 Mobility in soil: SEBACIC ACID (CAS#111-20-6): log Koc= 2.429
12.5 Results of PBT&vPvB assessment: Not available.
12.6 Other adverse effects: Not available.
Section 13 Disposal considerations
13.1 Waste treatment methods: The material should be disposed of by incineration in a chemical incinerator in
compliance with national and regional requirements.
Section 14 Transport information
| Land transport(ADR/RID) |
Sea transport (IMDG) |
Air transport (ICAO/IATA) | |
| UN-Number |
Not |
regulated |
Not |
| UN Proper shipping name |
Not |
regulated |
Not |
| Transport hazard Class |
Not |
regulated |
Not |
| Packaging group |
Not |
regulated |
Not |
| Environmental hazards |
No |
No |
No |
| Special precautions for user |
See section 2.2 |
See section 2.2 |
See section 2.2 |
| Transport in bulk according toAnnex II of Marpol and the IBCCode |
Not |
regulated |
Not |
Section 15 Regulation information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Relevant information regarding authorization: Not applicable.
Relevant information regarding restriction: Not applicable.
Other EU regulations: Employment restrictions concerning young person must be observed. For
use only by technically qualified individuals.
Other National regulations: Not applicable
15.2 Chemical Safety Assessment has been
carried out?
YES NO X
Section 16 Other information
16.1 Indication of changes:
Version 6.0 Amended by (EU) 2015/830
16.2 Training instructions:
Not applicable.
16.3 Further information:
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this
product.
16.4 Notice to reader:
Employers should use this information only as a supplement to other information gathered by them, and should make independent
judgment of suitability of this information to ensure proper use and protect the health and safety of employees. This information is
furnished without warranty, and any use of the product not in conformance with this Safety Data Sheet, or in combination with any
other product or process, is the responsibility of the user.
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